Elsevier, Chemical Physics, 2-3(279), p. 87-99
DOI: 10.1016/s0301-0104(02)00443-3
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The CH+CH4 and H2S reactions were studied, at room temperature, in a low-pressure fast-flow reactor. CH(X2Π,v=0) radicals were obtained from the reaction of CHBr3 with potassium atoms. The overall rate constants were found at 330 K to be (0.76±0.20)×10−10 and (2.8±0.8)×10−10cm3molecule−1s−1, respectively. The absolute atomic hydrogen productions were determined by resonance fluorescence in the vacuum ultraviolet: H production from the CH+CH4 reaction is 100% and from the CH+H2S reaction is 99+1−4%, the H production from the CH+H2 reaction being the reference. Ab initio studies of the different stationary points relevant to the CH+CH4 reaction have been performed at the CCSD(T)/cc-pVTZ level and comparison is made with experimental results. The experimental results for the CH+H2S reaction is compared with those of a recent theoretical study [Chem. Phys. 242 (1999) 1].