Published in
Elsevier, Journal of Molecular Structure, 1-3(525), p. 173-183
DOI: 10.1016/s0022-2860(00)00408-7
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Comparative study of the metal–ligand bond strength in MnII/X/U complexes (X=Cl, Br, I; U=urea)
Journal article published in 2000 by
R. Keuleers,
G. S. Papaefstathiou 
,
C. P. Raptopoulou,
S. P. Perlepes,
H. O. Desseyn
,
C. P. Raptopoulou,
S. P. Perlepes,
H. O. Desseyn
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Abstract
The synthesis, structure, vibrational analysis and a comparative vibrational study in function of the structure and the metal– ligand bond strength are discussed for a series of Mn(II)–urea–halogenide complexes. Complex [MnCl 2 U] has been prepared and studied for the first time. The single-crystal X-ray structure of the 1:6-bromide complex reveals the presence of octahedral [MnU 6 ] 2 ions and bromide counterions.