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Elsevier, Inorganic Chemistry Communications, 9(9), p. 915-919

DOI: 10.1016/j.inoche.2006.05.031

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Two 3D supramolecular architectures from zinc hydrogen aconitate 1D polymers

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This paper is available in a repository.

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Abstract

The reaction of Zn(NO3)2·3(H2O) with trans-aconitic acid, in presence of chelating Lewis bases, leads to the formation of the 1D polymers [Zn(N–N)(LH)]·nH2O, where LH3=trans-aconitic acid, 1 : N–N=1,10-phenanthroline (phen), n=1, 2 : N–N=2,2′-bipyridine (bpy), n=2. 3D supramolecular assemblies are constructed through H-bonding and stacking interactions.