The direct carbon fuel cells with solid oxide electrolyte (DC-SOFC) and anodes deposited by inject printing (EM/DCIJP) were studied. The cells were fed with carbon fuel obtained by the direct RF plasma splitting of methane. Since the (EM/DCIJP)M/DCIJP technology allows easy modification of electrode material, the effect of Cu addition to the Ni–YSZ anode was investigated. The significant improvement of the cell performance with the new anode was observed.