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Elsevier, Chemical Physics Letters, (585), p. 133-137, 2013

DOI: 10.1016/j.cplett.2013.08.098

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Absorption cross-sections of hole polarons in glassy and β-phase polyfluorene

Journal article published in 2013 by Francisco Montilla ORCID, Arvydas Ruseckas ORCID, Ifor D. W. Samuel ORCID
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

Absorption induced by electrochemically injected holes is studied in poly-9,9-dioctylfluorene (PFO) films. Injected charges form positive polarons which are delocalised over four fluorene units in the glassy phase and about seven fluorene units in its beta-phase. Polaron absorption cross-sections at the 640 nm peak are similar to the published values of chemically reduced oligofluorenes in solution. The absorption cross-section of polaron in the beta-phase at 470 nm is about eight times smaller than the stimulated emission cross-section derived from published data. This indicates that beta-phase-rich PFO is an attractive candidate for a lightemitting layer in double-heterostructure organic laser diodes.