Concentrations of noble gases, stable isotopes and 14C in samples from the Continental Terminal groundwaters of Niger provide evidence for more humid and cooler climate phases in West Africa in the Holocene and the late Pleistocene. During humid phases, even within the Holocene, the soil temperature was up to 5.5 degree C cooler than today, which is partly attributed to atmospheric cooling, but also to a change in the relationship between air and soil temperature due to increased vegetation. Intense rainfall events and increased groundwater recharge are consistently indicated by stable isotope data and excess air concentrations, i.e., the component of dissolved atmospheric gases in excess of solubility equilibrium. This finding encourages the use of excess air as an additional, humidity-related climate indicator.