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Published in

Taylor and Francis Group, Molecular Physics, 18(108), p. 2315-2323

DOI: 10.1080/00268976.2010.482066

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Submillimetre-wave spectrum of diacetylene and diacetylene-d2

Journal article published in 2010 by Luca Bizzocchi ORCID, Claudio Degli Esposti, Luca Dore
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

Full text: Unavailable

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Data provided by SHERPA/RoMEO

Abstract

Rovibrational bands between closely lying bending vibrational states of normal diacetylene and its bideuterated variant have been recorded in the submillimetre-wave region using a source-modulation spectrometer. The two isotopologues were produced by pyrolysis (1200C) of benzene or benzene-d6 vapour in a flow reactor. Measurements of the ν8 − ν6 band and of its ν9-associated hot band have been extended up to 615 and 420 GHz, respectively. Rotational and vibrational l-type resonance were taken into account in the analysis of the ν8 + ν9 − ν6 − ν9 band; in addition the cubic anharmonic resonance existing between the v8 = v9 = 1 state and the v3 = 1 stretching state has been considered explicitly in the least-squares fits to the observed frequencies. Very accurate values of the band origins and of numerous spectroscopic constants have been determined for both isotopologues.