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Elsevier, Tetrahedron: Asymmetry, 9(11), p. 1943-1955

DOI: 10.1016/s0957-4166(00)00143-9

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Optically active palladacycles containing imines derived from 1-(1-naphthyl)ethylamine: new resolving agents for P-chiral phosphines

Journal article published in 2000 by Joan Albert, J. Magali Cadena, J. Magali Cadena, Jaume R. Granell ORCID, Xavier Solans, Mercè Font-Bardia
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis of the new palladium metallacycles containing imines derived from 1-(1-naphthyl)ethylamine is reported. These new organometallic complexes have been used to resolve the P-chiral ligand benzylcyclohexylphenylphosphine. The absolute configuration of (RC,SP)-[PdCl{2-[HCN-CH(Me)C10H6]-3-ClC6H3}(PBzCyPh)] has been determined by single crystal X-ray analysis.