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Elsevier, Journal of Magnetism and Magnetic Materials, 1(323), p. 133-137

DOI: 10.1016/j.jmmm.2010.08.048

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Hydrothermal synthesis and magnetic properties of gadolinium-doped CoFe2O4 nanoparticles

Journal article published in 2011 by Jianhong Peng, Mirabbos Hojamberdiev ORCID, Yunhua Xu, Baowei Cao, Juan Wang, Hong Wu
This paper is available in a repository.
This paper is available in a repository.

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Abstract

CoFe2−xGdxO4 (x=0–0.25) nanoparticles were synthesized via a simple hydrothermal process at 200°C for 16h without the assistance of surfactant. The as-synthesized powders were characterized by X-ray diffraction, transmission electron microscopy, and a vibrating sample magnetometer. The X-ray diffraction results showed that the as-synthesized powders were in the pure phase with a doping amount of ≤0.25, and the peaks could be readily indexed to the cubic spinel cobalt ferrite. Transmission electron microscopy and high resolution transmission electron microscopy observations revealed that the gadolinium-doped cobalt ferrite nanoparticles were single crystal, roughly spherical, uniformly distributed, and not highly agglomerated. The room temperature magnetic field versus magnetization measurements confirmed a strong influence of gadolinium doping on the saturation magnetization and coercivity due to large lattice distortion and grain growth of small particles.