Elsevier, Ceramics International, 7(40), p. 9535-9540
DOI: 10.1016/j.ceramint.2014.02.027
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journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues. Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited. In most cases authors are permitted to post their version of the article (e.g. in Word or Tex form) to their personal website or institutional repository. Authors requiring further information regarding Elsevier's archiving and manuscript policies are encouraged to visit: Abstract In this work, TiO 2 (0–50 vol%) nanoparticles (25 nm) were added to a 11.7Li 2 O Á 12.6ZrO 2 Á 68.6SiO 2 Á 7.1Al 2 O 3 , LZSA (4 μm) glass-ceramic matrix to prepare composites in order to investigate the influence of TiO 2 on the sinterability, crystallinity and some properties to obtain information to design materials for low temperature co-fired ceramics (LTCCs) applications. The sintered composites (700–1000 1C/30 min) with relative densities between 95% and 98%, showed β-podumene,TiO 2 and L i2 TiSiO 5 as main crystalline phases. The maximum bending strength (235 7 84 MPa) was achieved for composites with 40% TiO 2 sintered at 1000 1C/30 min. The coefficient of thermal expansion increased linearly with the concentration of TiO 2 , i.e., 3.5 Â 10 À 6 1C À 1 for 0% TiO 2 and 9.5 Â 10 À 6 1C À 1 to 100% TiO 2 . The values of thermal conductivity were low and increased with the increase of the volumetric fraction of TiO 2 , reaching a maximum (3.30 W/mK) for samples (40% TiO 2) sintered at 1000 1C/30 min. The measurements of electrical conductivity indicate that the obtained materials are electrical insulators ($10 À 10 S cm À 1).