Published in

American Geophysical Union, Paleoceanography, 1(26), 2011

DOI: 10.1029/2009pa001902

Links

Tools

Export citation

Search in Google Scholar

Improving temperature estimates derived from Mg/Ca of planktonic foraminifera using X-ray computed tomography–based dissolution index, XDX

Journal article published in 2011 by Heather J. H. Johnstone, Jimin Yu ORCID, Henry Elderfield, Michael Schulz ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Orange circle
Published version: archiving restricted
Data provided by SHERPA/RoMEO

Abstract

1] Temperatures derived from Mg/Ca ratios of the calcite tests of planktonic foraminifera are distorted when samples are partially dissolved, and methods are required to quantify this source of inaccuracy. Here we compare a dissolution index (XDX), based on X‐ray computed tomography scans, to Mg/Ca of four species of foraminifera (G. ruber (white), G. sacculifer (without sac), N. dutertrei, and P. obliquiloculata) from core top sediments from the tropical Pacific, Atlantic, and western Indian Ocean. Deepwater calcite saturation values (D[CO 3 2− ]) at the sites ranged from 55 to −23 mmol/kg. An estimate of DMg/Ca (reduction in Mg/Ca due to dissolution) was made for each sample. DMg/Ca decreased linearly from deepwater D[CO 3 2− ] values of between 10 (±4) and 15 (±5) mmol/kg. These values are minimum estimates of the threshold below which Mg/Ca is affected by dissolution, as they are limited by assumptions made in calculating DMg/Ca. Sensitivity of Mg/Ca to D[CO 3 2− ] was greatest for G. ruber, where Mg/Ca decreased by 0.102 (±0.036) mmol/mol per mmol/kg. Sensitivity was similar for G. sacculifer (0.047 ± 0.015 mmol/mol per mmol/kg), N. dutertrei (0.037 ± 0.010 mmol/mol per mmol/kg), and P. obliquiloculata (0.040 ± 0.008 mmol/mol per mmol/kg). Sensitivity was similar at all sites for each species, excepting an apparently greater response for N. dutertrei from the Caribbean compared to other sites. Calibrations between XDX and DMg/Ca provide a means to estimate dissolution bias on Mg/Ca. Poor correlation between XDX and d 18 O suggests that, for the small sample size typical for analysis, variability in initial d 18 O overwhelms dissolution effects.