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Wiley, European Journal of Inorganic Chemistry, 6(2000), p. 1283-1286, 2000

DOI: 10.1002/(sici)1099-0682(200006)2000:6<1283::aid-ejic1283>3.3.co;2-3

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Resolution of Secondary Phosphanes Chiral at Phosphorus by Means of Palladium Metallacycles

Journal article published in 2000 by Joan Albert, J.??Magali Cadena, Jaume Granell ORCID, Guillermo Muller, David Panyella, Carolina Sañudo
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The synthesis of new epimeric compounds [PdCl(C−N){(±)-PHPhR}] (C−N = (R)-C10H6CHMeNH2 and (R)-C6H4CHMeNH2, R = Me and PhCH2) containing chiral secondary phosphanes is reported. Some of these diastereomers can be separated by column chromatography; subsequent reaction of these complexes with 1,2-bis(diphenylphosphanyl)ethane (dppe) affords the free phosphanes PHBzPh and PHMePh. The configurational stability of the secondary phosphanes resolved has also been studied.