Published in

American Institute of Physics, AIP Conference Proceedings, 2014

DOI: 10.1063/1.4866744

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A Versatile Electrochemical Method to Produce Nanoparticles of Manganese Oxides by KMnO4 Electrolysis

Proceedings article published in 2014 by Achmad Ralibi Tigor, Ni'mah Sakiynah, Heru Setyawan ORCID
This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

Various manganese oxides nanoparticles can be synthesized using a versatile electrochemical method. In this method, KMnO4 solution was electrolyzed using carbon electrodes at 60 degrees C. By only adjusting the solution pH, the nanoparticles obtained can be alpha-MnO2 or Mn2O3. In acid solution (pH similar to 4), the particles produced were alpha-MnO2. On the other hand, in basic solution (pH similar to 9), the particles produced were Mn2O3. Both alpha-MnO2 and Mn2O3 particles are nearly spherical in shape with surface area ranging from 71-157 m(2)/g and diameter 1579-188 nm. The surface area and diameter are influenced by the voltage during electrolysis. The higher the voltage, the larger the diameter particles are.