Dissemin is shutting down on January 1st, 2025

Published in

Elsevier, Journal of Molecular Spectroscopy, 2(241), p. 192-199

DOI: 10.1016/j.jms.2006.12.010

Links

Tools

Export citation

Search in Google Scholar

An analysis of the rotational, fine and hyperfine effects in the (0,0) band of the A7Π–X7Σ+ transition of manganese monohydride, MnH

Journal article published in 2007 by Jamie J. Gengler, Timothy C. Steimle, Jeremy J. Harrison ORCID, John M. Brown
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Orange circle
Postprint: archiving restricted
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

High-resolution (±0.003 cm−1), laser induced fluorescence (LIF) spectra of a supersonic molecular beam sample of manganese monohydride, MnH, have been recorded in the 17500–17800 cm−1 region of the (0, 0) band of the A7Π–X7Σ + system. The low-N branch features were modeled successfully by inclusion of the magnetic hyperfine mixings of spin components within a given low-N rotational level using a traditional ‘effective’ Hamiltonian approach. An improved set of spectroscopic constants has been extracted and compared with those from previous analyses. The optimum optical features for future optical Stark and Zeeman measurements are identified.