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Elsevier, Tetrahedron Letters, 16(53), p. 2132-2136

DOI: 10.1016/j.tetlet.2012.02.055

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Unexpected reactivity of trifluoromethylated olefins with indole: A mechanistic investigation

Journal article published in 2012 by Mónica S. Estevão, Filipe J. S. Duarte, Eduarda Fernandes ORCID, A. Gil Santos, A. Gil Santos, M. Manuela B. Marques
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Several trifluoromethylated compounds were reacted with indole sodium salt, leading to monofluorinated compounds. The unexpected products formation was rationalized by DFT calculations.