Published in
Springer, Photochemical & Photobiological Sciences, 1(10), p. 123-127, 2011
DOI: 10.1039/c0pp00284d
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Cationic and radical intermediates in the acid photorelease from aryl sulfonates and phosphates
Journal article published in 2010 by
Marco Terpolilli,
Daniele Merli,
Stefano Protti,
Valentina Dichiarante 
,
Maurizio Fagnoni,
Angelo Albini
,
Maurizio Fagnoni,
Angelo Albini
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Abstract
The irradiation of a series of phenyl sulfonates and phosphates leads to the quantitative release of acidity with a reasonable quantum yield (≈0.2). Products characterization, ion chromatography analysis and potentiometric titration are consistent with the intervening of two different paths in this reaction, viz. cationic with phosphates and (mainly) radical with sulfonates.