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Elsevier, Synthetic Metals, 1-3(115), p. 41-45

DOI: 10.1016/s0379-6779(00)00298-8

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Depolarizing energy transfer in photoluminescent polymer blends

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

The occurrence of a depolarizing polarizing energy transfer effect is demonstrated in uniaxially oriented polymer blend films. These blends are based on ultra-high molecular weight polyethylene as the matrix polymer, and additionally comprise 1,4-bis{(2-ethylhexyloxy)phenylethynyl} benzene (EHO-BPB) as a sensitizer, and either a regioregular HT sexi(3-n-octylthiophene) (6OT) or 7-(dimethylamino)-4-(trifluoromethyl) coumarin (C152) as emitter. The EHO-BPB sensitizer molecules are highly oriented in tensile-deformed blend films, and, thus, cause a highly anisotropic, i.e. linearly polarized optical absorption. The absorbed energy is, subsequently, transferred to the emitter molecules, which are essentially unoriented and, consequently, emit unpolarized light.