The clay deposit of Vila Nova da Rainha (VNR) is included in the lithostratigraphic formation named "Argilas de Tomar", and is located at the lower section of the Tertiary Tagus' river basin. Clay from one quarry is being extracted for the production of construction ceramics. In this work the firing transformations undergone by VNR clays containing quartz, alkaline feldspar, iron oxy-hydroxides, and clay minerals have been studied. Carbonates have not been identified in these raw materials. The clay layers can be subdivided in three groups based upon composition and ceramic properties. The first group, VNR0, is represented by smectite-kaolinite sandy-silty clay, the second group (VNR1 and VNR2) corresponds to illite-kaolinite bearing clay and the third group (VNR3 and VNR4) is represented by illite-smectite silty clay. The firing process involves the formation of hematite and mullite both influencing the technical properties of the fired products. With regards to the ceramic properties assessed at 1100 °C the first group showed the lowest total shrinkage value (7.35 %) the highest water absorption value (12.2 %) and the lowest mechanical bending strength value (12.0 MPa); the same properties assessed in the second group provided the highest firing shrinkage values (7.0-5.0 %), the lowest values of water absorption (0.1-0.2 %) and relatively high mechanical bending strength values (47.8-48.0 MPa); the third group showed firing shrinkage values within the range 3.5-4.2 %, water absorption values within the range 1.4-4.5 %, and the highest mechanical bending strength values (49.2-52.0 MPa). The results of the ceramic properties being appraised indicate that the raw materials being studied are suitable for the production of high-quality construction ceramics, such as brick, roof tile and rustic floor tile.