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De Gruyter, Zeitschrift für Kristallographie - Crystalline Materials, 7(228), p. 318-322, 2013

DOI: 10.1524/zkri.2013.1607

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Alcohol responsive 2D coordination network of 3-(4-pyridyl)benzoate and Zinc(II)

Journal article published in 2013 by Gift Mehlana, Gaëlle Ramon, Susan A. Bourne
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The solvothermal reaction of 3-(4-pyri-dyl)benzoic acid and zinc nitrate yielded a 2D network with an sql topology. Both elemental analysis and single crystal X-ray diffraction studies confirmed the formula of the compound as {[Zn(34pba) 2 ] Á (0.5 DMF) Á (0.5 H 2 O)} n (1). At room temperature, the desolvated phase of 1, 1d, ab-sorbs methanol, ethanol, 1-propanol and 1-butanol but not water vapour.