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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 6(64), p. m829-m830, 2008

DOI: 10.1107/s1600536808014268

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(Benzoato-κ2O,O′)(quinoline-2-carboxylato-κ2N,O)(quinoline-2-carboxylic acid-κ2N,O)copper(II)

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The crystal structure of the title compound, [Cu(C10H6NO2)(C7H5O2)(C10H7NO2)], contains copper(II) ions five-coordinated in a distorted trigonal-bipyramidal environment. The equatorial plane is occupied by three O atoms, one from the carboxyl­ate group of the benzoate ion considered as occupying a single coordination site, the other two from two carboxyl­ate groups of the quinaldic acid and quinaldate ligands. The axial positions are occupied by the N atoms of the quinoline ring system. The metal ion lies on a twofold axis that bisects the benzoate ion. The quinaldate and quinaldic acid ligands are equivalent by symmetry, and the carboxyl­ate/carboxyl groups are disordered. The disordered H atom is shared between the carboxyl­ate groups of adjacent quinaldic acid mol­ecules. Such hydrogen bonds delineate zigzag chains that run along the c axis. The structure is very similar to that of the MnII analog.