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Wiley, Angewandte Chemie International Edition, 22(41), p. 4337-4339, 2002

DOI: 10.1002/1521-3773(20021115)41:22<4337::aid-anie4337>3.0.co;2-k

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Isoprenoid Biosynthesis through the Methylerythritol Phosphate Pathway: The (E)-4-Hydroxy-3-methylbut-2-enyl Diphosphate Synthase (GcpE) is a [4Fe–4S] Protein

Journal article published in 2002 by Myriam Seemann, Bernadette Tse Sum Bui, Murielle Wolff, Denis Tritsch, Narciso Campos ORCID, Albert Boronat, Andrée Marquet, Michel Rohmer
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This paper is available in a repository.

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Abstract

One of the last bottlenecks in the elucidation of the methylerythritol phosphate pathway for isoprenoid biosynthesis has been solved. A [4Fe–4S] cluster is the prosthetic group of the GcpE protein from E. coli. This enzyme is involved in the conversion of 1 into 2, through two successive one-electron transfers.