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Wiley, Angewandte Chemie International Edition, 21(46), p. 3905-3908, 2007

DOI: 10.1002/anie.200604776

Wiley, Angewandte Chemie, 21(119), p. 3979-3982, 2007

DOI: 10.1002/ange.200604776

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Controlling the Sense of Enantioselection on Surfaces by Conformational Changes of Adsorbed Modifiers

Journal article published in 2007 by Angelo Vargas, Davide Ferri ORCID, Norberto Bonalumi, Tamas Mallat, Alfons Baiker
This paper is available in a repository.
This paper is available in a repository.

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Abstract

(Figure Presented) Shapeshifting: The sense of enantioselection in the asymmetric hydrogenation of activated ketones over modified platinum depends on the cinchona-alkaloid modifier (for example, O-phenylcinchonidine; see picture). Spectroscopic and theoretical studies reveal that the chiral space is reshaped through a change in the conformation of the modifier.