Synthesis of the Smallest Axially Chiral Molecule by Asymmetric Carbon-Fluorine Bond Activation
Journal article published in 2012 by
Moritz F. Kuehnel,
Tobias Schlöder,
Sebastian Riedel,
Belén Nieto-Ortega,
Francisco J. Ramírez 
,
Juan T. López Navarrete,
Juan Casado,
Dieter Lentz
,
Juan T. López Navarrete,
Juan Casado,
Dieter Lentz
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Abstract
Enantioselect-DeFluor: Carbon-fluorine bond cleavage by a chiral zirconium complex allows the synthesis of optically active 1,3-difluoroallene for the first time. Its absolute configuration was established by gas-phase vibrational circular dichroism spectroscopy.