Published in
Elsevier, Tetrahedron Letters, 29(44), p. 5515-5517
DOI: 10.1016/s0040-4039(03)01245-0
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Thermodynamic study on supramolecular complex formation of theophylline derivates with a synthetic receptor
Journal article published in 2003 by
Jeroni Morey,
Pablo Ballester 
,
Miquel Angel Barceló,
Antoni Costa ,
Pere M. Deyà
,
Miquel Angel Barceló,
Antoni Costa ,
Pere M. Deyà
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Abstract
Thermodynamic parameters for the supramolecular complex formation of macrobicyclophane with several theophylline dimers are reported. Solvation of guests plays an important role in the supramolecular complex formation. A good correlation between ΔG and guest solubility is obtained in different CHCl3/CH2Cl2 proportions.