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International Union of Crystallography, Acta Crystallographica Section E: Structure Reports Online, 7(68), p. o2260-o2261, 2012

DOI: 10.1107/s1600536812028735

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2-{2-[(E)-(2-Benzoyl­hydrazin-1-yl­idene)meth­yl]phen­oxy}acetic acid

Journal article published in 2012 by Hoong-Kun Fun ORCID, Tze Shyang Chia, Ahmed M. Alafeefy, Hatem A. Abdel-Aziz
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Postprint: archiving allowed
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Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

In the title compound, C16H14N2O4, the dihedral angle between the aromatic rings is 12.45 (6)°. The central C(=O)—N—N=C bridge is roughly planar (r.m.s. deviation = 0.0346 Å) and makes dihedral angles of 13.01 (7) and 0.56 (7)° with the attached phenyl and benzene rings, respectively. The acetic acid unit (r.m.s. deviation = 0.0066 Å) is twisted from its attached benzene ring [dihedral angle = 19.48 (6)°]. In the crystal, mol­ecules are linked by O—H⋯(O,N), N—H⋯O and C—H⋯O hydrogen bonds into sheets lying parallel to the bc plane. A weak aromatic π–π stacking inter­action is also observed [centroid–centroid distance = 3.7330 (7) Å].