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Elsevier, Tetrahedron Letters, 49(38), p. 8557-8560

DOI: 10.1016/s0040-4039(97)10283-0

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Acetyl Substituted Benzenes. Useful Cores for the Synthesis of Dendrimeric Polyketones.

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This paper is available in a repository.

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Abstract

Benzylation of acetyl substituted benzenes is an efficient route to dendrimeric polyketones. A benzyl bromide possessing a masked carbonyl group is the key reagent for the dendrimeric growth. π-Stacking in the crystals of the first generation from 1,4-diacetylbenzene is observed.