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Wiley, Advanced Materials, 37(21), p. 3759-3763, 2009

DOI: 10.1002/adma.200900326

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Polaron Localization at Interfaces in High‐Mobility Microcrystalline Conjugated Polymers

Journal article published in 2009 by N. Zhao, Y.-Y. Noh, J.-F. Chang, M. Heeney ORCID, I. McCulloch, H. Sirringhaus
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The charge-induced optical absorptions of two-dimensional polarons in semicrystalline, high-mobility conjugated polymers are investigated as a function of distance from an interface with polymer gate dielectrics of different dielectric constants. For high-k dielectrics, polarons in the accumulation layer at the interface are found to be more localized than those in the bulk.