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American Institute of Physics, Applied Physics Letters, 16(104), p. 161907

DOI: 10.1063/1.4873539

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Thermal conductivity of mesoporous films measured by Raman spectroscopy

Journal article published in 2014 by B. Stoib, S. Filser, N. Petermann, H. Wiggers, M. Stutzmann ORCID, M. S. Brandt
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We measure the in-plane thermal conductance of mesoporous Ge and SiGe thin films using the Raman-shift method and, based on a finite differences simulation accounting for the geometry of the sample, extract the in-plane thermal conductivity. For a suspended thin film of laser-sintered SiGe nanoparticles doped with phosphorus, we find an effective in-plane thermal conductivity of 0.05 W/m K in vacuum for a temperature difference of 400 K and a mean temperature of 500 K. Under similar conditions, the effective in-plane thermal conductivity of a laser-sintered undoped Ge nanoparticle film is 0.5 W/m K. Accounting for a porosity of approximately 50%, the normalized thermal conductivities are 0.1 W/m K and 1 W/m K, respectively. The thermoelectric performance is discussed, considering that the electrical in-plane conductivity is also affected by the mesoporosity.