Petrographic, mineralogical and geochemical studies have been carried out on beneficiated coal products from mines and preparation plants in the Santa Catarina Basin, southern Brazil, to investigate the range of characteristics exhibited by the materials and the potential impact of their stockpiling and storage on the environment. The coals contain varying proportions of vitrinite and inertinite macerals, and have vitrinite reflectance values ranging from 0.44 to 1.38%. With the exception of one material blended with peat from an external source, they have relatively high percentages of ash (30–58%) and mineral matter (36–66%). The mineral matter consists mainly of clay minerals (kaolinite, illite and illite/smectite), together with 15–25% quartz, up to 10% feldspar, up to 5% calcite and/or dolomite and up to 5% pyrite, and around 1% anatase and/or rutile. Bassanite is also present in low-temperature ash derived from the coals, mainly derived from interaction of Ca and S associated with the organic matter. Jarosite is formed by pyrite oxidation in coals that have been exposed in stockpiles for extended periods.