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Wiley, Chemistry - An Asian Journal, 11(9), p. 3116-3120, 2014

DOI: 10.1002/asia.201402777

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Large Magnetocaloric Effect in a Dense and Stable Inorganic-Organic Hybrid Cobridged by In Situ Generated Sulfate and Oxalate

Journal article published in 2014 by Song De Han, Xiao-Hong Miao, Sui-Jun Liu ORCID, Xian-He Bu
This paper is available in a repository.
This paper is available in a repository.

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Abstract

A dense and stable inorganic-organic hybrid with distorted cubic [Gd4 O4 ] units as building blocks bridged by in situ generated sulfate and oxalate was synthesized. Magnetic measurements indicate that the title complex features a -ΔSm (max) =51.49 J kg(-1) K(-1) , which is among the highest values reported so far.