Published in
Royal Society of Chemistry, RSC Advances, 14(5), p. 10763-10767, 2015
DOI: 10.1039/c4ra15458d
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Squashed {(Fe2M4III)-M-III} octahedra (M = Y, Gd, Dy) from the first use of the cyanoacetate ligand in 3d/4f coordination chemistry
Journal article published in 2015 by
Christina D. Polyzou,
Amer Baniodeh,
Nicola Magnani,
Valeriu Mereacre,
Nicolas Zill,
Christopher E. Anson,
Spyros P. Perlepes,
Spyros P. Perpeles,
Annie K. Powell
This paper is made freely available by the publisher.
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Abstract
The first use of the cyanoacetate ligand in 3d/4f-metal chemistry leads to {Fe2IIIM4III} (M = Dy, Gd, Y) coordination clusters with a squashed octahedral core structure; the DyIII compound exhibits slow relaxation of the magnetisation.