Published in
American Chemical Society, Inorganic Chemistry, 21(46), p. 8490-8492, 2007
DOI: 10.1021/ic7014034
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A Triply Interpenetrated Microporous Metal−Organic Framework for Selective Sorption of Gas Molecules
Journal article published in 2007 by
Banglin Chen,
Shengqian Ma 
,
Shengqian,
Eric J. Hurtado,
Emil B. Lobkovsky,
Hong-Cai Zhou
,
Shengqian,
Eric J. Hurtado,
Emil B. Lobkovsky,
Hong-Cai Zhou
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Abstract
A microporous metal-organic framework Zn(ADC)(4,4'-Bpe)(0.5).xG [1; ADC = 4,4'-azobenzenedicarboxylate, 4,4'-Bpe = trans-bis(4-pyridyl)ethylene, G = guest molecules] with a triply interpenetrative primitive cubic net was synthesized and characterized. With pores of about 3.4 x 3.4 A, the activated 1a exhibits highly selective sorption behavior toward H(2)/N(2), H(2)/CO, and CO(2)/CH(4).