Elsevier, Marine Chemistry, (171), p. 96-106, 2015
DOI: 10.1016/j.marchem.2015.02.013
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We performed an annual study of oxygenated volatile organic compound (OVOC) seawater concentrations at a site off Plymouth, UK in the Western English Channel over the period of February 2011 - March 2012. Acetone concentrations ranged from 2 - 10 nM (nanomoles/L) in surface waters with a maximum observed in summer. Concentrations correlated positively with net shortwave radiation and UV light, suggestive of photochemically linked acetone production. We observed a clear decline in acetone concentrations below the mixed layer. Acetaldehyde varied between 4 - 37 nM in surface waters with higher values observed in autumn and winter. Surface concentrations of methanol ranged from 16 - 78 nM, but no clear annual cycle was observed. Methanol concentrations exhibited considerable inter-annual variability. We estimate consistent deposition to the sea surface for acetone and methanol but that the direction of the acetaldehyde flux varies during the year.