Elsevier, Materials Letters, 22(64), p. 2520-2522
DOI: 10.1016/j.matlet.2010.07.077
Full text: Download
The homogeneity of hydrogen absorption for LaFe11.5Si1.5 intermetallic compound was investigated. The hydrides remained NaZn13-type structure when the hydrogenation temperature varied from 423K to 923K under 1atm hydrogen atmosphere. The Differential Scanning calorimetric (DSC) measurements revealed slightly inhomogeneous distribution of hydrogen atoms in the hydrides hydrogenated at a low temperature. The activation before hydrogenating at a higher temperature could improve the homogeneity of hydrogen absorption. Uniform magnetic transition temperature, corresponding to the homogeneous hydrogen absorption, was observed by hydrogenating the compound at 823K, or at 523K after activation. The maximum magnetic entropy change ΔSM (ΔH=2T) for the compound hydrogenated at 823K is about 15.5J/kg K with the latent heat of 5.12×103J/kg during the phase transition.