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Wiley-VCH Verlag, ChemInform, 31(38), 2007

DOI: 10.1002/chin.200731171

Elsevier, Tetrahedron, 14(63), p. 3010-3016

DOI: 10.1016/j.tet.2007.01.062

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Practical and Efficient Entry to Isoflavones by Pd(0)/C-Mediated Suzuki—Miyaura Reaction. Total Synthesis of Geranylated Isoflavones.

Journal article published in 2007 by Francois-Xavier Felpin ORCID, Cecile Lory, Hawaa Sow, Samir Acherar ORCID
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This paper is available in a repository.

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Abstract

A scalable synthesis of isoflavones taking advantage of the Suzuki–Miyaura reaction catalyzed by Pd(0)/C is described. The approach developed has been extended to the total synthesis of 7-O-geranylformononetin, griffonianone D, and conrauinone D, which did not display cytotoxicity against human HeLa carcinoma cells. In addition, this study established unambiguously the absolute configuration of natural griffonianone D.