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Elsevier, Solar Energy Materials and Solar Cells, 4(64), p. 385-392

DOI: 10.1016/s0927-0248(00)00231-2

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High efficiency dye-sensitized nanocrystalline solar cells based on sputter deposited Ti oxide films

Journal article published in 2000 by M. M. Gómez, J. Lu, E. Olsson ORCID, A. Hagfeldt, C. G. Granqvist
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Nanocrystalline solar cells were made by incorporation of cis-dithiocyanato-bis(2,2′-bipyridyl-4,4′-dicarboxylate) ruthenium (II) into sputter deposited titanium oxide films. After a pyridine treatment, it was possible to achieve a photoelectric conversion efficiency as high as 7% for a solar intensity of – almost the same as for conventional nanocrystalline cells with colloidally prepared titanium oxide. Transmission electron microscopy indicated a parallel penniform microstructure, and secondary ion mass spectroscopy showed that the dye incorporation was uniform except in the bottom parts of the sputtered films where a decreased porosity seems to limit the penetration of the dye.