Published in

SAGE Publications, Journal of Chemical Research, 5(37), p. 257-262, 2013

DOI: 10.3184/174751913x13639616845172

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Syntheses, characterisation and electrochemical properties of C<sub>70</sub>-metal cluster complexes

Journal article published in 2013 by Chang Yeon Lee ORCID
This paper is available in a repository.
This paper is available in a repository.

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Abstract

The complexes [Os3(CO)9( μ3- η2: η2: η2-C70)] and [Re3( μ-H)3(CO)9( μ3- η2: η2: η2-C70)] have been prepared by reaction of C70 with [Os3(CO)10(NCMe)2] or [Re3( μ-H)3(CO)11(NCMe)] and their electrochemical properties studied by cyclic voltammetry in chlorobenzene solutions. The complex [Re3( μ-H)3(CO)8(CNCH2Ph)( μ3- η2: η2: η2-C70)] has also been synthesised by reaction between [Re3( μ-H)3(CO)9( μ3- η2: η2: η2-C70)] and PhCH2N=PPh3.