Elsevier, Surface Science, 13(602), p. L84-L88
DOI: 10.1016/j.susc.2008.04.031
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The unusual adsorption geometry of the large graphene-like polycyclic aromatic hydrocarbon hexa-peri-hexabenzocoronene (HBC) across kinks on the stepped vicinal Au(111212) surface has been studied by synchrotron radiation X-ray photoelectron diffraction (XPD) and scanning tunneling microscopy (STM). By a combination of the two techniques a complete characterisation of the adsorption behaviour is achieved, yielding information on preferential adsorption sites (STM) and molecular orientation (XPD). At low coverage (