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Elsevier, Tetrahedron: Asymmetry, 16(20), p. 1912-1917

DOI: 10.1016/j.tetasy.2009.07.017

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Enantioselective alkylidenecyclopropanation of norbornenes with terminal alkynes catalyzed by palladium–phosphinous acid complexes

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This paper is available in a repository.

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Abstract

Pd(II)-coordinated phosphinous acids catalyzed the formal enantioselective [2+1] cycloaddition of norbornene derivatives with terminal alkynes. The absolute configuration of (+)-3aa was assigned using VCD.