Published in

The Royal Society, Philosophical Transactions of the Royal Society A: Mathematical, Physical and Engineering Sciences, 1782(359), p. 897-907

DOI: 10.1098/rsta.2001.0808

Links

Tools

Export citation

Search in Google Scholar

Beyond Simple Depletion: Phase Behaviour Of Colloid-Star Polymer Mixtures

This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Significant progress has been made in the last decade in understanding mixtures of hard–sphere colloids and (smaller) non–adsorbing ideal, linear polymers. We introduce extra complexity into this simple model system by replacing the linear polymers wit star–branched polymers with increasing functionality but constant radius of gyration. The observed phase diagrams, interprete in light of what is known about hard–sphere colloid plus linear polymer and binary–hard–sphere mixtures, suggest that 32–ar stars are close to behaving hard–sphere–like in colloid–star mixtures at this size ratio.