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American Physical Society, Physical review B, 24(92)

DOI: 10.1103/physrevb.92.241114

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Glass-ferroic composite caused by the crystallization of ferroic glass

Journal article published in 2015 by Yuanchao Ji, Xiangdong Ding, Dong Wang ORCID, Kazuhiro Otsuka, Xiaobing Ren
This paper is available in a repository.
This paper is available in a repository.

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Abstract

We report a glass-ferroic composite (in short “glass-ferroic”) in ferroic materials, an analog of the composite of glassy and crystalline phases (glass-crystal composite, e.g., semicrystalline polymer). The formation of glass-ferroic (i.e., the existence of residual ferroic glass) stems from a time-dependent crystallization of the ferroic glass. Moreover, glass-ferroics show two types of transition characteristics depending on the thermal hysteresis of crystallization transition as exemplified in Ti 48.7 Ni 51.3 and Pb 0.87 La 0.13 Zr 0.4 Ti 0.6 O 3 . Based on experimental results, a generic phase diagram is established to include all ferroic states, i.e., ferroic crystal, ferroic glass, and glass-ferroic. Being the third class of ferroic materials, glass-ferroics may open a new avenue for achieving novel properties and designing ferroic phase-change memory devices.