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Published in

European Geosciences Union, Atmospheric Chemistry and Physics, 16(11), p. 8471-8487, 2011

DOI: 10.5194/acp-11-8471-2011

European Geosciences Union, Atmospheric Chemistry and Physics Discussions, 4(11), p. 11379-11415

DOI: 10.5194/acpd-11-11379-2011

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Denitrification and polar stratospheric cloud formation during the Arctic winter 2009/2010

This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The sedimentation of HNO 3 containing Polar Stratospheric Cloud (PSC) particles leads to a permanent re-moval of HNO 3 and thus to a denitrification of the strato-sphere, an effect which plays an important role in strato-spheric ozone depletion. The polar vortex in the Arctic win-ter 2009/2010 was very cold and stable between end of De-cember and end of January. Strong denitrification between 475 to 525 K was observed in the Arctic in mid of January by the Odin Sub Millimetre Radiometer (Odin/SMR). This was the strongest denitrification that had been observed in the entire Odin/SMR measuring period (2001–2010). Lidar measurements of PSCs were performed in the area of Kiruna, Northern Sweden with the IRF (Institutet för Rymdfysik) li-dar and with the Esrange lidar in January 2010. The measure-ments show that PSCs were present over the area of Kiruna during the entire period of observations. The formation of PSCs during the Arctic winter 2009/2010 is investigated us-ing a microphysical box model. Box model simulations are performed along air parcel trajectories calculated six days backward according to the PSC measurements with the ground-based lidar in the Kiruna area. From the temperature history of the backward trajectories and the box model simu-lations we find two PSC regions, one over Kiruna according to the measurements made in Kiruna and one north of Scan-dinavia which is much colder, reaching also temperatures be-low T ice . Using the box model simulations along backward Correspondence to: F. Khosrawi (farah@misu.su.se) trajectories together with the observations of Odin/SMR, Aura/MLS (Microwave Limb Sounder), CALIPSO (Cloud-Aerosol Lidar and Infrared Pathfinder Satellite Observations) and the ground-based lidar we investigate how and by which type of PSC particles the denitrification that was observed during the Arctic winter 2009/2010 was caused. From our analysis we find that due to an unusually strong synoptic cooling event in mid January, ice particle formation on NAT may be a possible formation mechanism during that particu-lar winter that may have caused the denitrification observed in mid January. In contrast, the denitrification that was ob-served in the beginning of January could have been caused by the sedimentation of NAT particles that formed on moun-tain wave ice clouds.