Published in

American Physical Society, Physical review E: Statistical, nonlinear, and soft matter physics, 2(80)

DOI: 10.1103/physreve.80.021401

Links

Tools

Export citation

Search in Google Scholar

Cluster formation and bulk phase behavior of colloidal dispersions

Journal article published in 2009 by Tao Jiang, Jianzhong Wu ORCID
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
Green circle
Postprint: archiving allowed
Green circle
Published version: archiving allowed
Data provided by SHERPA/RoMEO

Abstract

We investigated cluster formation in model colloids where the interparticle potential beyond the collision diameter includes a short-ranged attraction and a longer-ranged repulsion. The structure and thermodynamic properties of the model system can be accurately described by the first-order mean-spherical approximation (FMSA) and a perturbation theory for bulk phases and by a nonlocal density-functional theory (DFT) for stable/metastable clusters. In corroboration with recent experiments and molecular simulations, we predicted that the bulk to cluster transition may occur at both one-phase and two-phase regions of the colloidal phase diagram. While formation of colloidal clusters appears uncorrelated with the bulk phase transitions, the local phenomena may nevertheless play an important role in the dynamics of stable colloids and the kinetics of colloidal phase transitions.