Published in

IOP Publishing, Journal of Physics: Condensed Matter, 47(15), p. 8095-8102

DOI: 10.1088/0953-8984/15/47/012

Links

Tools

Export citation

Search in Google Scholar

The ferroelectric soft mode and central mode in SrBi<sub>2</sub>Ta<sub>2</sub>O<sub>9</sub>films

Journal article published in 2003 by M. Kempa ORCID, P. Ku el, S. Kamba ORCID, P. Samoukhina, J. Petzelt, A. Garg, Z. H. Barber
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Red circle
Preprint: archiving forbidden
Red circle
Postprint: archiving forbidden
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

The dynamics of the ferroelectric phase transition in a SrBi2Ta2O9 film of 5.5 µm thickness deposited on sapphire was studied by means of time-domain terahertz transmission spectroscopy (30–300 K) and Fourier transform far-infrared transmission spectroscopy (300–950 K). The optical soft mode near 28 cm−1 (at 300 K) exhibits a weak monotonic softening down to 20 cm−1 at 950 K with no significant anomaly near either the ferroelectric or ferroelastic phase transition. An additional relaxation process below the phonon frequencies was resolved in the terahertz transmission spectra. The critical slowing down of its relaxation frequency could be responsible for the dielectric anomaly near the ferroelectric transition temperature. This indicates that the ferroelectric transition is predominantly of order–disorder type.