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American Physical Society, Physical Review Letters, 1(96), 2006

DOI: 10.1103/physrevlett.96.017006

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Structures and Potential Superconductivity inSiH4at High Pressure: En Route to “Metallic Hydrogen”

This paper was not found in any repository, but could be made available legally by the author.
This paper was not found in any repository, but could be made available legally by the author.

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Abstract

A way to circumvent the high pressures needed to metallize hydrogen is to "precompress" it in hydrogen-rich molecules, a strategy probed theoretically for silane. We show that phases with tetrahedral SiH4 molecules should undergo phase transitions with sixfold- and eightfold-coordinate Si appearing above 25 GPa. The most stable structure found can be metallized at under a megabar and at a compression close to the prediction of Goldhammer-Herzfeld criterion. According to a BCS-like estimate, metallic silane should be a high-temperature superconductor.