Elsevier, Proceedings of the Combustion Institute, 2(34), p. 2839-2846, 2013
DOI: 10.1016/j.proci.2012.07.079
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Chemical looping combustion (CLC) uses a metal oxide (the oxygen carrier) to provide oxygen for the combustion of a fuel and gives an inherent separation of pure CO 2 with minimal energy penalty. In solid-fuel CLC, volatile matter will interact with oxygen carriers. Here, the interaction between iron-based oxy-gen carriers and a volatile hydrocarbon (n-heptane) was investigated in both a laboratory-scale fluidised bed and a thermogravimetric analyser (TGA). Experiments were undertaken to characterise the thermal decomposition of the n-heptane occurring in the presence and in the absence of the oxygen carrier. In a bed of inert particles, carbon deposition increased with temperature and acetylene appeared as a possible precursor. For a bed of carrier consisting of pure Fe 2 O 3 , carbon deposition occurred once the Fe 2 O 3 was fully reduced to Fe. When the Fe 2 O 3 was doped with 10 mol % Al 2 O 3 (Fe90Al), deposition started when the carrier was reduced to a mixture of Fe and FeAl 2 O 4 , the latter being very unreactive. Furthermore, when pure Fe 2 O 3 was fully reduced to Fe, agglomeration of the fluidised bed occurred. However, Fe90Al did not give agglomeration even after extended reduction. The results suggest that Fe90Al is promising for the CLC of solid fuels.