Dissemin is shutting down on January 1st, 2025

Published in

American Chemical Society, ACS Applied Materials and Interfaces, 29(7), p. 15716-15725, 2015

DOI: 10.1021/acsami.5b00679

Links

Tools

Export citation

Search in Google Scholar

Decoration of Micro-/Nanoscale Noble Metal Particles on 3D Porous Nickel Using Electrodeposition Technique as Electrocatalyst for Hydrogen Evolution Reaction in Alkaline Electrolyte

Journal article published in 2015 by Xin Qian ORCID, Tao Hang, Sangaraju Shanmugam ORCID, Ming Li
This paper is available in a repository.
This paper is available in a repository.

Full text: Download

Green circle
Preprint: archiving allowed
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Orange circle
Postprint: archiving restricted
  • Must obtain written permission from Editor
  • Must not violate ACS ethical Guidelines
Red circle
Published version: archiving forbidden
Data provided by SHERPA/RoMEO

Abstract

Micro/nano-scale noble metal (Ag, Au, Pt) particles decorated 3D porous nickel electrodes for hydrogen evolution reaction (HER) in alkaline electrolyte are fabricated via galvanostatic electrodeposition technique. The developed electrodes are characterized by field emission scanning electron microscopy and electrochemical measurements including Tafel polarization curves, cyclic voltammetry and electrochemical impedance spectroscopy. It is clearly shown that the enlarged real surface area due to 3D highly porous dendritic structure has greatly reinforced the electrocatalytic activity towards HER. Comparative analysis of electrodeposited Ag, Au and Pt particles decorated porous nickel electrodes for HER indicates that both intrinsic property and size of the noble metal particles can lead to distinct catalytic activities. Both nano-scale Au and Pt particles have further reinforcement effect towards HER, whereas micro-scale Ag particles exhibits reverse effect. As an effective 3D hydrogen evolution cathode, nano-scale Pt particles decorated 3D porous nickel electrode demonstrates the highest catalytic activity with an extremely low overpotential of -0.045 V for hydrogen production, a considerable exchange current density of 9.47 mA cm-2 at 25 oC and high durability in long-term electrolysis, which are attributed to the intrinsic catalytic property and the extremely small size of Pt particles.