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Elsevier, Journal of Physics and Chemistry of Solids, 10(69), p. 2356-2359

DOI: 10.1016/j.jpcs.2008.03.015

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Effect of on the growth and thermal properties of K2SO4 crystal

Journal article published in 2008 by S. Bin Anooz, D. Klimm ORCID, M. Schmidbauer, R. Bertram, M. Roßberg
This paper is available in a repository.
This paper is available in a repository.

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Abstract

Single crystals of pure and Cd2+ doped potassium sulfate were grown from aqueous solutions by the slow evaporation technique. From nutrient solutions with a CdSO4 concentration of 4wt.% crystals containing 0.014wt.% dopant concentration could be obtained. The X-ray diffraction patterns of powdered crystals confirmed their crystal structures for both cases. Thermal analysis of pure crystals shows that the alpha-beta phase transformation peak around 580 deg C is superimposed with spurious effects, while for Cd2+ doped crystals this is not the case. The thermal hysteresis of the phase transition is 8 K for undoped K2SO4 and is reduced to 3.5 K for K2SO4:Cd2+. Compared to undoped crystals, the optical transmittance of Cd2+ doped crystals is higher. Comment: 5 pages, 6 figures