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Wiley, Angewandte Chemie International Edition, 44(45), p. 7358-7364, 2006

DOI: 10.1002/anie.200601991

Wiley, Angewandte Chemie, 44(118), p. 7518-7524, 2006

DOI: 10.1002/ange.200601991

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High H2 Adsorption by Coordination‐Framework Materials

Journal article published in 2006 by Xiang Lin Dr, Xiang Lin, Junhua Jia, Xuebo Zhao ORCID, Xuebo Zhao Dr, K. Mark Thomas Prof. Dr, K. Mark Thomas, Alexander J. Blake Dr ORCID, Gavin S. Walker Dr, Neil R. Champness Prof. Dr, Peter Hubberstey Dr, Peter Hubberstey, Martin Schröder Prof. Dr, Martin Schröder
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Abstract

First-class accommodation: A series of coordination frameworks with different pore sizes (see structure of one; Cu blue, C gray, H white, O red) are prepared from CuII ions and carboxylate ligands of various lengths. Comparison of their sorption properties reveals that smaller pores allow higher densities of adsorbed H2, whereas larger pores allow higher maximum H2 storage capacities. (Figure Presented).