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Royal Society of Chemistry, RSC Advances, 9(5), p. 6501-6504, 2015

DOI: 10.1039/c4ra15588b

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Photocatalytic Hydroxylation of Arylboronic Acids using Continuous Flow Reactors

Journal article published in 2014 by Inès Geerte Thea Maria Penders, Zacharias Amara, Raphael Horvath ORCID, Kai Rossen, Martyn Poliakoff, Michael W. George
This paper is made freely available by the publisher.
This paper is made freely available by the publisher.

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Abstract

The photocatalytic oxidation of mono- and di-substituted arylboronic acids to phenols has been investigated using a continuous flow photoreactor fitted with white LEDs. An EtOH/H2O solvent system accelerated conversion at 2 MPa; whereas reactions at atmospheric pressure allowed for efficient desymmetrisation.